Kristall- und Molekülstruktur von N,N'-Bis(1,3-dimethylbenzo[d]-1,3,2-diaza-borolidin-2-yl)carbodiimid

Publication Type
Journal contribution
Authors
Sawitzki, G.; Einholz, W.; Haubold, W.
Year of publication
1988
Published in
Z. Naturforsch., B: Chem. Sci.
Band/Volume
43/9
Page (from - to)
1179-83
Abstract

Crystals of the title compd. I are monoclinic. The mol. I neither has a C2-sym. allene-type nor a D2d-sym. cumulene-type structure, but it has a non-linear B-N=C=N-B arrangement and is nearly planar. The central N=C=N angle has a value of 171.9(3).degree., the B-N=C angles are 145.9(2).degree. and 163.1(3).degree..

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