Resin-bound anionically induced Domino reactions; synthesis of functionalized carbocyclic compounds

Publication Type
Journal contribution
Authors
Gutke, H.-J.; Spitzner, D.
Year of publication
1999
Published in
Tetrahedron
Band/Volume
55/13
Page (from - to)
3931-3936
Abstract

The anionically induced domino reaction of resin-bound Li-dienolate with an α-halo-α,β-unsatd. ester gave the corresponding immobilized tricyclo[3.2.1.02,7]octane, which can be olefinated or oxidized. The cycles are cleaved from the resin by acid.

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