Diazaborolidyl - a stable substituent at sulfur-nitrogen compounds
- Publikations-Art
- Zeitschriftenbeitrag
- Autoren
- Haubold, W.; Fehlinger, H. G.; Frey, G.
- Erscheinungsjahr
- 1981
- Veröffentlicht in
- Z. Naturforsch., B: Anorg. Chem., Org. Chem.
- Band/Volume
- 36B/2
- Seite (von - bis)
- 157-60
2-Chlordiazaborolidine (I) and N-silylated sulfur nitrogen compds. with sulfur in the 4+ or 6+ oxidn. state react to give thermally-stable boranes, e.g. Me2S(O):NB(NMeCH2)2 and O:C:NB(NMeCH2)2. Reactions with other chlorboranes like (Me2N)2BCl, II, Ph2BCl or PhBCl2 gave less stable or unstable compds.