A simple synthesis of a functionalized tricyclo[5.2.2.01,5]undecene as a synthon for isoeremolactone
- Publikations-Art
- Zeitschriftenbeitrag
- Autoren
- Weber, W.; Spitzner, D.; Kraus, W.
- Erscheinungsjahr
- 1980
- Veröffentlicht in
- J. Chem. Soc., Chem. Commun.
- Band/Volume
- 24/
- Seite (von - bis)
- 1212-3
The ester I, a synthon for the diterpene isoeremolactone, was prepd. (80%) from the racemic ketone II by sequential double Michael addn. of Me acrylate, thioacetalization, redn., tolylsulfonylation, and solvolysis.